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COURSE OUTLINE
KMU 501
- Advanced Chemical Engineering Thermodynamics
FALL
SEMESTER
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INSTRUCTOR: |
Dr. ÖNEL, Selis
| selis@hacettepe.edu.tr
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TEACHING ASSISTANT: |
Not assigned. |
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COURSE GOALS: |
Students will review basic
thermodynamic principles as well as increase their knowledge and
gain new skills in:
- First and second laws
- Thermodynamics of solutions
- Chemically reacting systems
- Thermodynamic property
estimation
Students will learn and use MATLAB
as a tool (using built-in functions) for solving numerical
problems |
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COURSE MAIN TEXTBOOK: |
Currently, a main course textbook
is not assigned and the students have the option to choose any
of the supplementary textbooks for the course. The
preferred textbook is Tester and Modell's book due to its
advanced content. |
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SUPPLEMENTARY TEXTBOOKS: |
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- S. I. Sandler, Chemical
and Engineering Thermodynamics, 3rd edition, Wiley, 1999
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SCHEDULE: |
KMU
501
Thursday........ 12.30 PM - 2.45 PM with one 15 minute break (Seminar
Room) |
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CONTENT: |
Introduction, the scope of classical thermodynamics, basic
concepts and definitions
Conservation of mass and energy, first law of thermodynamics
Reversibility and the second law of thermodynamics
Equilibrium criteria
Stability criteria
Thermodynamics of multicomponent mixtures
Phase equilibrium in mixtures
Vapor-liquid equilibrium modeling with two parameter cubic
equations of state and the van der Waals mixing rules
Mixing rules that combine an equation of state with an activity
coefficient model
Chemical equilibrium and the balance equations for chemically
reacting systems |
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OBJECTIVES: |
Students will become competent with using phase equilibria,
thermodynamic solution models and multi-component systems. |
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COURSE FORMAT:
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The course will consist of classroom instruction including
lectures using classical lecture style, power point slides, and
simultaneous Matlab applications via projection. Additional
computer lab and tutorial hours may be held upon request. |
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DATE OF MIDTERM:
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1st
Midterm:
Written in class exam
2nd
Midterm:
Project |
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GRADING:
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Quizes + Homeworks..............................................25%
Midterm I
............................................................25%
Project + Midterm II +
Final
Exam.............................50%
Total..................................................................100%
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USEFUL LINKS: |
- Thermodynamic look-up
tables and charts
- KMU 206 Numerical Analysis
Methods
course web site
- MATLAB
tutorial
- Thermodynamic
course notes, University of NewCastle
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Course Outline |
Week# |
Topics |
1 |
PPt Slides |
Course
objectives and starting as a engineering graduate in research |
2
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PPt Slides |
Introduction, the scope of
classical thermodynamics,
Review of thermodynamic concepts,
basic definitions, equations of state |
3
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Class notes |
Mechanical reversibility, Conservation of mass and energy, first law of thermodynamics
Enthalpy, heat capacity of an
ideal gas, First law and the concept of work
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4
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Class notes |
Thermodynamic properties:
Extensive, intensive, measurable, and conceptual
Heat capacity of incompressible
liquids and solids
Calculation of and relation
between boundary work and shaft work |
5
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Class notes |
Compressibility factor, Principal
of corresponding states
Equations of state and Virial
equations
Generalized enthalpy correction
Applications of virial equations,
Extended virial equation
Cubic equations of state:
van der Waals equation of state, a
generic cubic equation of state |
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6 |
Class notes |
Reversibility and the second law of thermodynamics,
1st, 2nd, 3rd and 4th axioms
Examples: Two heat reservoirs, Two
heat reservoirs with heat engine, Heat Pump
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7
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Class notes |
Second law of thermodynamics
continued: Entropy balance
Carnot, Kelvin, Clasius
statements, Equilibrium criteria and Stability criteria
Entropy of an ideal gas, Carnot
cycle for an ideal gas, Otto cycle
Fundamental condition of
equilibrium |
8 |
Class notes |
Concept of Entropy continued:
Calculation of lost work
Fundamental property relation,
Combined statement of the first and second laws
Calculation of entropy changes,
generalized entropy correlation |
9
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Class notes |
Third law of thermodynamics
Entropy from microscopic point of
view
Quantitative expression of
disorder: Boltzmann and Gibbs examples |
10
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